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Beilstein J. Org. Chem. 2013, 9, 1891–1896, doi:10.3762/bjoc.9.222
Graphical Abstract
Scheme 1: Design of the planar chiral P,N-ligand.
Scheme 2: Synthesis of planar chiral P,N-ligand (Sp)-L1.
Scheme 3: Pd-catalyzed asymmetric allylic alkylation and amination reactions with (Sp)-L1.